Journal of Zhejiang University SCIENCE A
(Monthly)
2006 Vol. 7 No. 11 p. 1956-1960
ISSN 1009-3095(Print), 1862-1775(Online)CdS/SiO2 nanowire arrays and CdS nanobelt synthesized by thermal evaporation
YU Ling-min†1,2, ZHU Chang-chun2, FAN Xin-hui1, QI Li-jun1, YAN Wen1
(1School of Materials and Chemical Engineering, Xi’an Institute of Technology, Xi’an 710032, China)
(2School of Electronic and Information Engineering, Xi’an Jiaotong University, Xi’an 710049, China)
†E-mail: ylmyl@163.com
Received Dec. 8, 2005 revision accepted May 29, 2006
Abstract: CdS/SiO2 nanowire arrays and CdS nanobelts were synthesized by thermal evaporation of CdS and CdO mixture powders, with highly selective etching occurring on the silicon substrate surfaces. Study of the growth mechanism of CdS/SiO2 nanowire arrays and the growth process of CdS nanobelts showed that the growth of CdS dendrites plays an important role in the formation of CdS/SiO2 nanowire arrays, and that the mechanism of CdS/SiO2 nanowire arrays growth was in good agreement with “self-assembling nanoelectrochemistry”. In the thermal evaporation process, an interaction between Si from silicon substrate and Cd took place.
Key words: CdS/SiO2 nanowire arrays, CdS nanobelts, CdS dendrites, Self-assembling nanoelectrochemistry
doi:10.1631/jzus.2006.A1956 CLC number: TQ12
References:
[1] Dong, L.F., Jiao, J., 2003. Catalytic growth of CdS nanobelts and nanowires on tungsten substrates. Chemical Physics Letters, 376(5):653-658.
[2] Fu, X., Wang, D.B, Wang, J., Shi, H.Q., Song, C.X., 2004. High aspect ratio CdS nanowires synthesized in microemulsion system. Materials Research Bulletin, 39(12): 1869-1874.
[3] Fu, X.L., Li, L.H., Tang, W.H., 2006. Preparation and characterization of CdS/Si coaxial nanowires. Solid State Communications, 138(3):139-142.
[4] Gan, H.Y., Liu, H.B., Li, Y.L., 2004. Template synthesis and characterization of chiral organic nanotubes and nanowires. Chemical Physics Letters, 399(1):130-134.
[5] Ge, J.P., Li, Y.D., 2004. Selective atmospheric pressure chemical vapor deposition route to CdS arrays, nanowires, and nanocombs. Advanced Functional Materials, 14(2):157-162.
[6] Jin, K.W., Yao, B.D., Wang, N., 2005. Structural characterization of mesoporous silica nanowire arrays growing in porous alumina templates. Chemical Physics Letters, 409(4-6):172-176.
[7] Li, X.M., Chu, H.B., Li, Y., 2006. Sacrificial template growth of CdS nanotubes from Cd(OH)2 nanowires. Journal of Solid State Chemistry, 179(1):96-102.
[8] Peng, K.Q., Zhu, J., 2003. Simultaneous gold deposition and formation of silicon nanowire arrays. Journal of Electro-analytical Chemistry, 558(20):35-39.
[9] Soumitra, K., Tandra, G., Subhadra, C., 2006. Simple thermal evaporation route to synthesize Zn and Cd metal nanowires. Chemical Physics Letters, 419(2):174-178.
[10] Wang, Q.Q., Xu, G., Han, G.R., 2005. Solvothermal synthesis and characterization of uniform CdS nanowires in high yield. Journal of Solid State Chemistry, 178(9):2680- 2685.
[11] Wu, G.S., Yuan, X.Y., Xie, T., Xia, G.C., Zhang, L.D., 2004. A simple synthesis route to CdS nanomaterials with different morphologies by sonochemical reduction. Materials Letters, 58(5):794-797.
[12] Xu, D.S., Xu, Y.J., Chen, D.P., Guo, G.L., 2000. Preparation and characterization of CdS nanowire arrays by DC electrodeposit in porous anodic aluminum oxide templates. Chemical Physics Letters, 325(4):340-344.
[13] Yang, Y., Chen, H.L., Mei, Y.F., Chen, J.B., Wu, X.L., Bao, X.M., 2002. Anodic alumina template on Au/Si substrate and preparation of CdS nanowires. Solid State Communications, 123(6-7):279-282.
[14] Yang, X.H., Wu, Q.S., Li, L., Ding, Y.P., Zhang, G.X., 2005. Controlled synthesis of the semiconductor CdS quasi-nanospheres, nanoshuttles, nanowires and nanotubes by the reverse micelle systems with different surfactants. Colloids and Surfaces A: Physicochem. Eng. Aspects, 264(1-3):172-178.